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中国福彩网3d:Hexafluorosilicic acid

Hexafluorosilicic acid
Hexafluorosilicic acid structure
CAS No.
16961-83-4
Chemical Name:
Hexafluorosilicic acid
Synonyms
ACTH;ACTH 1-39;Sand acid ;CORTICOTROPHIN;CORTICOTROPIN A;FLUOROSILIC ACID;FLUOSILICIC ACID;Fluorsilicic acid;FLUOROSILICIC ACID;SILICOFLUORIC ACID
CBNumber:
CB3726895
Molecular Formula:
F6H2Si
Formula Weight:
144.09
MOL File:
16961-83-4.mol

Hexafluorosilicic acid Properties

Boiling point:
108-109°C
Density 
1.22 g/mL at 25 °C
refractive index 
1.3500
Flash point:
108-109°C
storage temp. 
−20°C
solubility 
H2O: 1 mg/mL, clear, colorless
form 
Liquid
Specific Gravity
1.38 (40%)
color 
Clear colorless
Water Solubility 
Miscible with water.
Hydrolytic Sensitivity
0: forms stable aqueous solutions
Merck 
14,4182
Stability:
Stable in aqueous solution.
InChIKey
AUJBMDCSBIPDEH-UHFFFAOYSA-N
CAS DataBase Reference
16961-83-4(CAS DataBase Reference)
EWG's Food Scores
1
EPA Substance Registry System
Fluosilicic acid (16961-83-4)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07,GHS05,GHS06
Signal word  Danger
Hazard statements  H302-H311-H314-H318
Precautionary statements  P260h-P301+P330+P331-P405-P501a-P280-P301+P312+P330-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C
Risk Statements  34-35-20/21/22
Safety Statements  26-36/37/39-45-27
RIDADR  UN 1778 8/PG 2
WGK Germany  3
RTECS  VV8225000
8-10
Hazard Note  Corrosive
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  28111990
Toxicity LD50 oral in rat: 430mg/kg

Hexafluorosilicic acid price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 372757 Fluorosilicic acid solution 20-25 wt. % in H2O 16961-83-4 500g $53.1 2019-12-02 Buy
Sigma-Aldrich 01302 Fluosilicic acid purum, 33.5-35% 16961-83-4 1l $58.9 2019-12-02 Buy
Alfa Aesar 069109 Hexafluorosilicic acid, 23% w/w aq. soln. 16961-83-4 500g $47.5 2019-12-02 Buy
Alfa Aesar L14829 Hexafluorosilicic acid, 35% w/w aq. soln. 16961-83-4 500g $47.5 2019-12-02 Buy
Sigma-Aldrich 01302 Fluosilicic acid purum, 33.5-35% 16961-83-4 6x1l $293 2019-12-02 Buy

Hexafluorosilicic acid Chemical Properties,Uses,Production

Description

Hexafluorosilicic acid is a kind of inorganic acid. It is majorly used for the fluoridation of water in United State to minimize the incidence of dental caries and dental fluorosis. For chemical synthesis, it is majorly used for the manufacturing of aluminum fluoride and cryolite as well as many kinds of hexafluorosilicate salts. It can also be used for the production of silicon and silicon dioxide. It can also be used as an electrolyte in the Betts electrolytic process for refining lead. It is also a specialized reagent in organic synthesis for cleaving Si–O bonds of silyl ethers.

Chemical Properties

Fluosilicic acid,H2SiF6, also known as hydrofluorosilicic acid,is a colorless liquid that is soluble in water. It is highly corrosive and toxic,attacking glass and stoneware. Fluosilicic acid is used in water fluoridation, electroplating, and in manufacturing enamels and cement.

Chemical Properties

Fluorosilicic acid is a transparent, colorless fuming liquid.

Uses

A 1-2% solution is used widely for sterilizing equipment in brewing and bottling establishments. Other concentrations are used in the electrolytic refining of lead, in electroplating, for hardening cement, crumbling lime or brick work, for the removal of lime from hides during the tanning process, to remove molds, as preservative for timber.

General Description

A colorless fuming liquid with a penetrating pungent odor. Corrosive to metals and tissue. Both the fumes and very short contact with the liquid can cause severe and painful burns. Used in water fluoridation, in hardening cement and ceramics, as a wood preservative.

Air & Water Reactions

Fumes in air. Soluble in water with release of heat and corrosive fumes.

Reactivity Profile

Hexafluorosilicic acid can react with strong acids (such as sulfuric acid) to release fumes of toxic hydrogen fluoride. Attacks glass and materials containing silica. Reacts exothermically with chemical bases (examples: amines, amides, inorganic hydroxides). Reacts with active metals, including iron and aluminum to dissolve the metal and liberate hydrogen and/or toxic gases. Can initiate polymerization in certain alkenes. Reacts with cyanide salts and compounds to release gaseous hydrogen cyanide. Flammable and/or toxic gases are also often generated by reactions with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and weak or strong reducing agents. Additional gas-generating reactions may occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and carbonates. Can catalyze (increase the rate of) chemical reactions. Decomposes when heated to the boiling point to produce very toxic and corrosive hydrogen fluoride gas.

Hazard

Extremely corrosive by skin contact and inhalation.

Health Hazard

Inhalation of vapor produces severe corrosive effect on mucous membrane. Ingestion causes severe burns of mouth and stomach. Contact with liquid or vapor causes severe burns of eyes and skin.

Fire Hazard

Special Hazards of Combustion Products: Irritating fumes of hydrogen fluoride may form in fire.

Industrial uses

Hydrofluorosilicic acid (H2SiF6) is a colorless to light brown liquid. It is also manufactured from calcium fluoride or other fluoride-containing products. Hydrofluorosilic acid is a strong depressant for many silicates during flotation of a number of oxidic minerals. It is used for gangue depression during flotation of tin, columbite and tantalite.

Safety Profile

Poison by subcutaneous route. A corrosive irritant to sktn, eyes, and mucous membranes. Will react with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of F-. See also FLUORIDES.

Potential Exposure

A solution of fluorosilicic acid is used for sterilization in the brewing and bottling industry, elec trolytic refining of lead; electroplating, hardening cement; removing mold, and others.

Shipping

UN1778 Fluorosilicic acid, Hazard class: 8; Labels: 8-Corrosive material.

Incompatibilities

The aqueous solution is a strong acid. Reacts with water or steam to produce toxic and corrosive fumes of hydrogen fluoride. Incompatible, and may react violently with: bases, aliphatic amines; alkanolamines, alkylene oxides; aromatic amines; amides, ammonia, ammonium hydroxide; calcium oxide; epichlorohydrin, iso cyanates, oleum, organic anhydrides; sulfuric acid; strong oxidizers; vinyl acetate; water. Attacks glass, concrete, and ceramics. The anhydrous form dissociates almost instantly into silicon tetrafluoride and hydrogen fluoride.

Waste Disposal

Add slowly to a large amount of soda ash in solution. Discharge to sewer with large volumes of water

References

Robinson, Tim. "Innovative Processes in Electrometallurgy." Innovative Process Development in Metallurgical Industry. Springer International Publishing, 2016. 385- 392.
Sarawade, Pradip B., et al. "Recovery of high surface area mesoporous silica from waste hexafluorosilicic acid (H 2 SiF 6) of fertilizer industry." Journal of hazardous materials 173.1 (2010): 576-580.
Kauffman, Joel M. "Water fluoridation: a review of recent research and actions." Journal of American Physicians and Surgeons 10.2 (2005): 38.
Krot, V. V., et al. "ChemInform Abstract: Preparation of Amorphous Silicon Dioxide from Hexafluorosilicic Acid." Cheminform 23.48(1992):no-no.
Zorya, L., and V. Krot. "Method of high-purity silica production from hexafluorosilicic acid." Reaction Kinetics & Catalysis Letters 50.1-2(1993):349-354.

Hexafluorosilicic acid Preparation Products And Raw materials

Raw materials

Preparation Products


Hexafluorosilicic acid Suppliers

Global( 200)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
[email protected]enchem.com CHINA 21806 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 [email protected] CHINA 22631 55
career henan chemical co
+86-371-86658258
[email protected] CHINA 30054 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 [email protected];[email protected];[email protected];[email protected] CHINA 23978 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 [email protected] CHINA 28235 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 [email protected] CHINA 8721 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 [email protected] CHINA 23048 58
Chongqing Chemdad Co., Ltd
+86-13650506873
[email protected] CHINA 35438 58
Mainchem Co., Ltd. +86-0592-6210733
+86-0592-6210733 [email protected] CHINA 32445 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 [email protected] China 24984 65

View Lastest Price from Hexafluorosilicic acid manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-20 Hexafluorosilicic acid
16961-83-4
US $1.00 / kg 1kg 95%-99% 100kg career henan chemical co

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